The Man from U.N.C.L.E.

S4 E9: The Fiery Angel Affair

In a Latin American country, Illya and Solo try to help the popular national leader, Angela (Madlyn Rhue) protect her government from the Secret Three, a revolutionary group backed by THRUSH. Solo is captured by the Secret Three, but escapes after learning that Vinay (Victor Ludlin), a friend of Angela's is plotting against her. He tells her husband, General Abaca (Joe Sirola), but the general is actually the one plotting to overthrow his wife's government and have her killed.